Identificación de compuestos orgánicos emergentes: desarrollo e implementación de metodologías para análisis por cromatografía de líquidos o gases

MARTHA AVILÉS FLORES NORMA RAMIREZ SALINAS (2011, [Documento de trabajo])

Las sustancias activas de los fármacos son una clase nueva de los así llamados contaminantes emergentes que se han incrementado en los últimos años. Las drogas veterinarias y humanas son continuamente liberadas en el ambiente como resultado de los procesos de fabricación, la disposición de productos no usados o expirados y en las excretas. La cantidad de fármacos y sus metabolitos bioactivos está siendo introducida al ambiente en pequeñas cantidades. Sin embargo, su continua introducción puede conducir a altas concentraciones a largo plazo y de forma continua, pero los efectos adversos no han pasado inadvertidos en los organismos acuáticos y terrestres. Dado la potencial peligrosidad de los fármacos en el medio ambiente, se requiere de metodologías analíticas capaces de determinar dichos compuestos a niveles traza, razón por la cual en el presente trabajo se implementa y valida la determinación de los fármacos amoxicilina, diclofenaco mediante cromatografía de líquidos y hormonas tales como 17ß-estradiol y el 17α-etinilestradiol, acetato de 17ß-estradiol y estrona, en agua potable y agua residual mediante cromatografía de gases y extracción en fase sólida.

Compuestos orgánicos Contaminantes emergentes Cromatografía de gases Cromatografía de líquidos INGENIERÍA Y TECNOLOGÍA

Synthesis of hollow carbon spheres by chemical activation of carbon nanoparticles for their use in electrochemical capacitor

Cesar Eduardo Sanchez Rodriguez EDUARDO TOVAR MARTINEZ MARISOL REYES REYES Luis Felipe Cházaro Ruiz ROMAN LOPEZ SANDOVAL (2022, [Artículo])

"Naphthalene combustion has been used to synthesize grams per hour of solid carbon spheres (CS). The carbon soot was activated by acid treatment consisting in a mixture of HNO3 and H2SO4 (1/3 v/v) to produce hollow carbon spheres (HCS). The effect of two concentrations of CSs (5 and 10 mg mL−1) in the acid mixture, on the physicochemical properties of the activated HCSs was studied. The HSCs were subjected to a thermal treatment to increase their graphitization to enhance their electrical conductivity. High-resolution transmission electron microscopy confirmed the formation of HCSs due to the acid treatment whereas FTIR spectra showed that the chemical activation produced functional groups on the carbon spheres surface and the heat treatment effect to remove some of them as well. A specific surface area of 300 m2 g−1 and a large density of micropores for the acid-treated CSs as well as the heat-treated CSs were estimated by analysis of N2 adsorption-desorption isotherms. A specific capacitance 70 F g−1 was calculated by cyclic voltammetry of the acid and thermally treated HCSs at 5 mV s−1, for both CS concentrations, indicating the possibility of synthesizing these HCSs using a simple method in large quantities for their use in electrochemical capacitors."

Physicochemical properties Carbon nanoparticles Chemical activation Electrochemical capacitor BIOLOGÍA Y QUÍMICA QUÍMICA QUÍMICA

Desarrollo de metodologías por cromatografía de gases para la identificación y cuantificación de compuestos orgánicos clorados en aguas residuales y municipales

MARTHA AVILÉS FLORES NORMA RAMIREZ SALINAS (2011, [Documento de trabajo])

Introducción – Fuentes de contaminantes emergentes – Fuentes puntuales – Fuentes no puntuales – Problemática de los fármacos en aguas residuales – Compuestos farmacéuticos reguladores de lípidos – Fármacos veterinarios – Objetivo – Metodología – Implementación de las metodologías – Resultados – Discusión – Conclusiones – Anexos – Bibliografía.

Industria farmacéutica Cromatografía de gases Compuestos orgánicos clorados Contaminantes emergentes Fuentes puntuales de contaminación Fuentes no puntuales de contaminación Informes de proyectos INGENIERÍA Y TECNOLOGÍA

Physiological ecology of Mexican CAM plants: history, progress, and opportunities

Joel David Flores Rivas Oscar Briones Villareal JOSE LUIS ANDRADE (2022, [Artículo])

"In Mexico, plants with crassulacean acid metabolism (CAM) are part of the Mexican culture, have different uses and are even emblematic. Unfortunately, only a small fraction of the Mexican CAM plants has been studied physiologically. For this review, the following questions were considered: What ecophysiological studies have been conducted with CAM species native to Mexico? What ecophysiological processes in Mexican CAM plants are the most studied? What type of ecophysiological studies with CAM plants are still needed? A database of scientific studies on CAM plant species from Mexico was documented, including field and laboratory works for species widely distributed, and those studies made outside Mexico with Mexican species. Physiological processes were grouped as germination, photosynthesis, and water relations. Most studies were done for CAM species of Cactaceae, Bromeliaceae, Asparagaceae and Orchidaceae, andmost ecophysiological studies have been done on germination of cacti. Field and laboratory studies on photosynthesis and water relations were mostly for terrestrial cacti and epiphytic bromeliads. There were few physiological studies with CAM seedlings in Mexico and few studies using stable isotopes of water and carbon of CAM plants in the field. More field and laboratory studies of physiological responses and plasticity of CAM plants to multiple stress factors are required to model plant responses to global climate change. In general, more physiological studies are essential for all CAM species and for species of the genus Clusia, with C3-CAM and CAM members, which can become ecologically important under some climate change scenarios."

Asparagaceae Bromeliaceae Cactaceae Germination Photosynthesis Water relations Orchidaceae BIOLOGÍA Y QUÍMICA CIENCIAS DE LA VIDA BIOLOGÍA VEGETAL (BOTÁNICA) BIOLOGÍA VEGETAL (BOTÁNICA)

Gobernanza de múltiple escala para la gestión local del agua de consumo humano en América Latina: estudios de caso en Costa Rica, Honduras y México

Multilevel governance for local management of drinking water in Latin America: case studies from Costa Rica, Honduras and Mexico

FERNANDO GUMETA GOMEZ ELVIRA DURAN MEDINA David Brayden (2017, [Artículo])

El abastecimiento del agua para consumo humano a escala local puede depender de la participación social. Se compararon tres regímenes de gobernanza para gestión del agua basado en acción colectiva y en entidades anidadas: 1) Asociaciones Administradoras de Sistemas de Acueductos y Alcantarillados Sanitario (ASADAS) en Costa Rica, 2) Juntas Ad-ministradoras del Agua (JAA) en Honduras y 3) Comités de Agua (CA) en Oaxaca, México. Se analizaron el marco legal, la estructura y operatividad y la eficiencia en la provisión y conservación de los recursos hídricos mediante revisión documental, observación partici-pativa y entrevistas informales.ASADAS y JAA son reconocidas legalmente, mientras que los CA no tienen soporte en el marco legal mexicano. Los regímenes mostraron estructuras y operatividad análoga, así como tendencias similares hacia eficiencia en la provisión del agua y en asegurar la recarga hídrica, pero capacidades económicas diferentes. Reconocer y empoderar los CA en México podría aumentar y garantizar el abastecimiento de agua a el largo plazo

Adequate supply of drinking water at local level depends, in many cases on community participation. We compare three governance regimes for drinking water management based on multilevel collective action: 1) ASADAS in Costa Rica, 2) Water Boards (JAA, for its acronym in spanish) in Honduras and 3) Water User Committees (CA, for its acronym in spanish) in Mexico. Our data is based on participant observation, and formal and informal interviews. Legal framework, structure and operation, and efficiency for provision and conservation of water resources are analyzed. ASADAS and Water Boards are legal entities with recog-nized community participation and collective action, while Water Committees have no legal support by the Mexican Government. Regimens showed similar structures and operation, but different economic capabilities and efficiencies in the provision of water and in ensur-ing water recharge. Recognition and empowerment of the Water Committees in Mexico could increase and ensure water provision in the long- term

HUMANIDADES Y CIENCIAS DE LA CONDUCTA Abasto de agua Gobernanza local Comités de agua Oaxaca Sustentabilidad de agua Water supply Local governance Water committees Oaxaca Sustainability of water

Advancing the science and practice of ecological nutrient management for smallholder farmers

Sieglinde Snapp (2022, [Artículo])

CIENCIAS AGROPECUARIAS Y BIOTECNOLOGÍA AGROECOLOGY DEGRADATION NUTRIENT CYCLES NUTRIENT USE EFFICIENCY SOIL ORGANIC MATTER SMALLHOLDERS

Precise irrigation water and nitrogen management improve water and nitrogen use efficiencies under conservation agriculture in the maize-wheat systems

Mahesh Gathala ML JAT (2023, [Artículo])

A 3-year field experiment was setup to address the threat of underground water depletion and sustainability of agrifood systems. Subsurface drip irrigation (SDI) system combined with nitrogen management under conservation agriculture-based (CA) maize-wheat system (MWS) effects on crop yields, irrigation water productivity (WPi), nitrogen use efficiency (NUE) and profitability. Grain yields of maize, wheat, and MWS in the SDI with 100% recommended N were significantly higher by 15.8%, 5.2% and 11.2%, respectively, than conventional furrow/flood irrigation (CT-FI) system. System irrigation water savings (~ 55%) and the mean WPi were higher in maize, wheat, and MWS under the SDI than CT-FI system. There was saving of 25% of fertilizer N in maize and MWS whereas no saving of N was observed in wheat. Net returns from MWS were significantly higher (USD 265) under SDI with 100% N (with no subsidy) than CT-FI system despite with higher cost of production. The net returns were increased by 47% when considering a subsidy of 80% on laying SDI system. Our results showed a great potential of complementing CA with SDI and N management to maximize productivity, NUE, and WPi, which may be economically beneficial and environmentally sound in MWS in Trans-IGP of South Asia.

Subsurface Drip Irrigation Nitrogen Management Irrigation Water Productivity Water Savings CIENCIAS AGROPECUARIAS Y BIOTECNOLOGÍA IRRIGATION WATER NITROGEN-USE EFFICIENCY CONSERVATION AGRICULTURE MAIZE WHEAT

THE RIGHT TO THE CITY AND URBAN-RURAL LINKAGES. COMMUNITY PARTICIPATION IN THE METROPOLITAN AREA OF TUXTLA GUTIERREZ, CHIAPAS.

Briseida Corzo Rivera Gabriel Castañeda Nolasco (2023, [Artículo, Artículo])

Access to water is a common struggle of the communities in the state of Chiapas, with the effects of urban expansion these struggles increase and with them the challenges that these populations already face, having a greater impact on the rural environment. The struggles to satisfy this basic need are a factor that has triggered processes that promote community participation. Based on a qualitative analysis, this paper compares two existing forms of participation in the rural communities of the Metropolitan Area of Tuxtla Gutierrez that allow the population to manage actions to improve their quality of life. The objective is to analyze how these processes promote or restrict the empowerment of the community and allow progress, not only in the population's access to water, but also in the construction of the right to the city. From the urban-rural linkages, the right to the city is discussed beyond the city, addressing other territories. The study identifies factors that show changes in the participation of the populations and strengthen the community, as well as factors in the relationships of the community and of the community with other actors that limit the scope of the processes.

Participation Right to the city Urban-rural linkages Access to water participación, derecho a la ciudad, vínculos urbano-rurales, acceso al agua. CIENCIAS SOCIALES CIENCIAS SOCIALES

Soil CO2 efflux fluctuates in three different annual seasons in a semideciduous tropical forest in Yucatan, Mexico

El flujo de CO2 del suelo fluctúa en tres temporadas del año en un bosque tropical semideciduo de Yucatán, México

Fernando Arellano-Martín JUAN MANUEL DUPUY RADA ROBERTH ARMANDO US SANTAMARIA José Luis Andrade Torres (2022, [Artículo])

Tropical forest soils store a third of the global terrestrial carbon and control carbon dioxide (CO2) terrestrial effluxes to the atmosphere produced by root and microbial respiration. Soil CO2 efflux varies in time and space and is known to be strongly influenced by soil temperature and water content. However, little is known about the influence of seasonality on soil CO2 efflux, especially in tropical dry forests. This study evaluated soil CO2 efflux, soil temperature, and soil volumetric water content in a semideciduous tropical forest of the Yucatan Peninsula under two sites (flat areas close to and far from hills), and three seasons: dry, wet, and early dry (a transition between the rainy and dry seasons) throughout a year. Additionally, six 24-h periods of soil CO2 efflux were measured within these three seasons. The mean annual soil CO2 efflux was 4±2.2 μmol CO2 m-2 s-1, like the mean soil CO2 efflux during the early dry season. In all seasons, soil CO2 efflux increased linearly with soil moisture, which explained 45% of the spatial-temporal variation of soil CO2 efflux. Soil CO2 efflux was higher close to than far from hills in some months. The daily variation of soil CO2 efflux was less important than its spatial and seasonal variation likely due to small diel variations in temperature. Transition seasons are common in many tropical dry forests, and they should be taken into consideration to have a better understanding of the annual soil CO2 efflux, especially under future climate-change scenarios. © 2022 Mexican Society of Soil Science. All Rights Reserved.

EARLY DRY SEASON SOIL TEMPERATURE SOIL VOLUMETRIC WATER CONTENT TROPICAL DRY FOREST BIOLOGÍA Y QUÍMICA CIENCIAS DE LA VIDA BIOLOGÍA VEGETAL (BOTÁNICA) ECOLOGÍA VEGETAL ECOLOGÍA VEGETAL

Estimating lime requirements for tropical soils: Model comparison and development

Fernando Aramburu Merlos João Vasco Silva Frédéric Baudron Robert Hijmans (2023, [Artículo])

Acid tropical soils may become more productive when treated with agricultural lime, but optimal lime rates have yet to be determined in many tropical regions. In these regions, lime rates can be estimated with lime requirement models based on widely available soil data. We reviewed seven of these models and introduced a new model (LiTAS). We evaluated the models’ ability to predict the amount of lime needed to reach a target change in soil chemical properties with data from four soil incubation studies covering 31 soil types. Two foundational models, one targeting acidity saturation and the other targeting base saturation, were more accurate than the five models that were derived from them, while the LiTAS model was the most accurate. The models were used to estimate lime requirements for 303 African soil samples. We found large differences in the estimated lime rates depending on the target soil chemical property of the model. Therefore, an important first step in formulating liming recommendations is to clearly identify the soil property of interest and the target value that needs to be reached. While the LiTAS model can be useful for strategic research, more information on acidity-related problems other than aluminum toxicity is needed to comprehensively assess the benefits of liming.

Exchangeable Acidity Aluminum Saturation Calcium Carbonate Equivalent CIENCIAS AGROPECUARIAS Y BIOTECNOLOGÍA CHEMICOPHYSICAL PROPERTIES LIMES TROPICAL ZONES ACID SOILS ALUMINIUM BASE SATURATION CALCIUM CARBONATE